CuAgAu complexes
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General synthesis procedure
There are different routes to synthesize complexes with reactive cations.
The direct way is a methathesis reaction. The reaction is activated by ultrasonication over 48 h at room temperature:
To create a complex with a very weak ligand it is neccesary to start from a "start material“:
A further method to synthesize the complex is via ligand abstraction. The syntheses starting with Al(ORF)3 must be cooled to -10°C and instead of ultravibration the mixture is stirred for 12 h:
More details:
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